Density Functional Theory Investigations of the Homoleptic Tris(dithiolene) Complexes [M(dddt)3]−q(q= 3, 2 ; M = Nd3+and U3+/4+) Related to Lanthanide(III)/Actinide(III) Differentiation

The structures of the homoleptic lanthanide and actinide tris(dithiolene) complexes [M(dddt)(3)](q-) (q = 3, M = Nd(3+) and q = 3 or 2, M = U(3+/4+)) have be...