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article · 2011

C(sp3)O Bond‐Forming Reductive Elimination of Ethers from Bisphosphine‐Ligated Benzylpalladium(II) Aryloxide Complexes

On the contrary: Isolated benzylpalladium aryloxide complexes undergo C(sp3)O bond-forming reductive elimination by a stepwise ionic mechanism (see scheme) ...

58 citationsDOI: https://doi.org/10.1002/anie.201101088
C(sp3)O Bond‐Forming Reductive Elimination of Ethers from Bisphosphine‐Ligated Benzylpalladium(II) Aryloxide Complexes