Stereospecific Deuteration of Chelated 2,2′-Thiodiacetate(tda) in [Co(dien)(tda)]+ (dien = diethylenetriamine) Observed in the Acidic D2O Solutions

Abstract Stereospecific deuteration rates of 2,2′-thiodiacetate (tda) in s-fac- and u-fac-[Co(dien)(tda)]+ were measured at 70.2 °C in D2O (pD range 4.4 – 6....