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article · 2008

Controlling the Activation of White Phosphorus: Formation of Phosphorous Acid and Ruthenium‐Coordinated 1‐Hydroxytriphosphane by Hydrolysis of Doubly Metalated P4

Successfully tamed: When coordinated to two {CpRu(PPh3)2} moieties, white phosphorus (P4) reacts selectively with a large excess of water to yield phosphorou...

45 citationsDOI: https://doi.org/10.1002/anie.200800723
Controlling the Activation of White Phosphorus: Formation of Phosphorous Acid and Ruthenium‐Coordinated 1‐Hydroxytriphosphane by Hydrolysis of Doubly Metalated P4