High-field EPR study and crystal and molecular structure of trans-RSSR-[CrCl2(cyclam)]nX (X = ZnCl42−, Cl−and Cl−·4H2O·0.5HCl)

For the first time, HF-EPR (94.5 GHz) spectroscopy has been used to determine crystal field parameters in chromium(III) coordination compounds. The large zer...